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  Evolution of Quantum States    


The inner product allows us to calculate probabilities for the outcome of a measurement provided that we know the ket describing hypothetical measurement at the time of measurement. This is only useful if we can calculate the ket at any time, t, from a known previous measurement result. The probability interpretation requires that time evolution is determined from a first order wave equation, the Schrödinger equation. Relativistic considerations dictate that Newton’s first law is obeyed for non-interacting particles.

Linearity of Time Evolution

Hilbert space refers to measurement at time, t, so that Evolution-1, where a different Hilbert space is required at each time. Bold type will be used for 3-vectors. For the time being, it will be assumed that the scale on which quantum mechanics applies is such that curvature can be ignored, so that position coordinates can be denoted by displacement vectors in Minkowski spacetime. Position states at time x0 = t will be denoted Evolution-2.

Definition:  If at time t0 the ket is Evolution-3g in H1(t0), then the ket Evolution-4g at time t is given by the time evolution operator, U(tt0) : H1(t0) → H1(t1), such that Evolution-5g.

If the state at time t0 was either Evolution-6 or Evolution-7, then it will evolve into either Evolution-8 or Evolution-9 at time t. Any weighting in quantum logical OR will be preserved, i.e., if
Evolution-10
then
Evolution-11
So,
Evolution-12
In words, U is a linear operator.

Continuity of Time Evolution

Irrespective of whether a model of discrete particle interactions might appear continuous on the large scale, the evolution of kets is expected to be continuous because kets are not physical states of matter, but are rather probabilistic statements about what might happen in measurement, given current information. According to modern Bayesian» ideas, probabilities» describe our ideas concerning the likelihood of events. They not a direct description of physical reality. Whether or not reality is fundamentally discrete, changes in probability can be properly described on a mathematical continuum. A discrete interaction will not lead to a discrete change in probability because we do not have information on when the interaction takes place. This being so, time evolution will be modelled by an continuous operator valued function of time, U. Together with the considerations below, continuity is sufficient to ensure differentiability (formal proof omitted).

At this point we have only states of a single, non-interacting particle. Subsequent pages will allow states containing an indefinite number of particles, and interactions betwen them. It is assumed that all phsysical systems will can be modeled in the same way. Since local laws of physics are always the same, and U does not depend on the state on which it acts, the evolution operator for a time interval t,
Evolution-17
does not depend on t0. We require that the evolution in an interval t1 + t2 is the same as the evolution in t1 followed by the evolution in t2, and is also equal to the evolution in t2 followed by the evolution in t1.
Evolution-18
In a zero time interval, there is no evolution. So, U(0) does not change the state.
Evolution-19
Using a negative value of t reverses time evolution (put t = t1 = −t2).
Evolution-20

Unitarity of Time Evolution

Since states can be chosen to be normalised we may require that U conserves the norm, i.e. for all Evolution-21,
Evolution-22
Applying this to Evolution-23,
Evolution-24
By linearity of U,
Evolution-25
By linearity of the inner product,
Evolution-26
Evolution-27
Similarly,
Evolution-28
Evolution-29
Evolution-28
Combining these results,
Evolution-31
So U is unitary.

Stone’s Theorem

The derivative of U is
Evolution-32
Evolution-33
Evolution-34
This prompts the definition of the Hamiltonian» operator, which does not depend on t.

Definition:  The Hamiltonian operator H : H1(t)→H1(t) is
Evolution-36g

We have
Evolution-36
So
Evolution-37
Since U is unitary, for a small time dt,
Evolution-38
Evolution-39
Ignoring terms in squares of dt, and using Evolution-40, Evolution-41,
Evolution-42
Using unitarity of U, we find that H is Hermitian, iH = H. We have the differential equation,
Evolution-44
which has solution (as for a differential equation of a function)
Evolution-45
This result was first proved by proved by Marshall Stone» in 1932, and is known as Stone’s theorem».

The Heisenberg Picture

I have formulated quantum theory in such a way that states evolve in time and observable operators are assumed to be constant. This is the Schrödinger picture». A precisely equivalent formulation, the Heisenberg picture» is found by a unitary transformation. States in the Heisenberg picture are defined by
Evolution-84
and are constant. Then, an observable operator, A, in the Schrödinger picture, is given in the Heisenberg picture by
Evolution-85
It is immediately clear that the result of calculation of probabilities is the same in both pictures,
Evolution-86
Switching between the Schrödinger and Heisenberg pictures is simply a change of basis, and is precisely equivalent to coordinate transformation.

The Wave Function

It follows from linearity of U that the evolution of the ket Evolution-13 from an initial state Evolution-14 at time t0 can be described in terms of its coefficients in a basis of position kets Evolution-15 at time x0 = t, by using the resolution of unity,
Evolution-16
On the assumption that the resolution of measurement may be arbitrarily fine, we define the wave function.

Definition:  The wave function is the map f : R4→C given by:
Evolution-55g

Theorem:  The wave function satisfies the Schrödinger Equation,
Evolution-92g

Proof: Differentiate the wave function using Stone’s theorem,
Evolution-93

Newton’s First Law

According to the general principle of relativity, the laws of physics are the same for any two observers. In particular, any two observers can define coordinates in exactly the same way, using identical physical procedures. They formally describe probabilities for measurement results using quantum logic. Given the same information, they must calculate the same probabilities irrespective of their motion with respect to each other. So, the calculation of probabilities is constrained by relativistic considerations. In special relativity, it was found that 3-vectors must be replaced with 4-vectors. Applying this to plane wave states (assuming an inertial reference frame and Minkowski metric), we find that a plane wave» evolves in the usual manner,
Evolution-46
where E2 = (p0)2 = m2 + p2 for some constant m. Thus, p does not change in time,
Evolution-48
establishing Newton’s first law. E is identified with energy and m with mass.

Definition:  The mass shell condition is the vector identity,
m2 = E2 − p2.

Wave Mechanics

To find the evolution of a ket from an initial state, Evolution-49, at t = 0, calculate the momentum space wave function using the resolution of unity,
Evolution-50
Then, using the resolution of unity in momentum space,
Evolution-51
By linearity of the time evolution operator, U,
Evolution-52
The coefficients are
Evolution-53
Evolution-54
Thus, the momentum space wave function is constant in time. If we know the ket from a measurement at time t = 0, we can calculate the ket for a measurement at any other time, and hence probabilities for the results of measurement at any time, by the usual methods of wave mechanics.

This does not say that there is a physical wave. Quite the reverse, the appearance of complex numbers shows we are talking of mathematics, not of Nature, until such point as calculated probabilities are related to the freqencies of measurement results. It does show that quantum interference effects are simply the result of constructing a probability theory for measurements of position in such a way that any two observers, given the same information, will find the same probabilities for corresponding measurements. This suggests that quantum interference patterns are a manifestation of the fundamental structure of spacetime formed through the interactions of particles which make it possible to describe relative position. Exactly how this happens and leads also to curvature in general relativity and the force of gravity is the focus of study in relational quantum gravity.

Evolution of Quantum States ↑The Dirac Equation →

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